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More subtly, it seems that the degree to which these pause durations are variable sites boundaries on the number of kinetic transitions which have been rate-restricting below distinct ATP concentrations – a end result very first proved by Aldous and Shepp in the context of queuing concept.111 This limit is captured by a quantity that We've got termed n
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min values only present lower limitations on the volume of kinetic gatherings. Nonetheless, reconciling the binding of 4 ATPs with a measured price of ∼2 requires the chemically identical subunits will not bind ATP With all the exact same costs. The catalytic performance (
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